Dicyclohexylamine Tail Gas Refining Method-manufacture,factory,supplier from China

The invention relates to a tail gas refining method, especially a method for hydrogenation of aniline to produce dicyclohexylamine tail gas deamination and hydrogen refining, which belongs to the technical field of chemical industry.

Devices that use tail gas to recover cyclohexylamine are characterized in that they include: spray tower, circulating pump, condenser, defogger, photooxygen catalytic oxidizer, ozone treatment device, blower, chimney. Described in the circulating pump and spray the bottom connection, as described in the other side of the circulating pump are connected to the condenser, the condenser and the upper spray tower connection, described in the spray tower are connected to the top of demister, described in the mist bottom and photocatalytic oxidation, photocatalytic oxidation is described, ozone

The process relates to a tail gas refining method, in particular to the hydrogenation of aniline to prepare cyclohexylamine and the deamination of dicyclohexylamine tail gas to refine hydrogen.

The invention relates to a synthesis method of dicyclohexylamine, which comprises the following steps: in a hydrogenation reactor, aniline and hydrogen are hydrogenated in gas phase under the catalyst to obtain DCHA crude product.The replacement reaction was carried out with aniline and DCHA crude product to obtain the replacement mother liquor. The replacement mother liquor was delight and refined, and DCHA product was obtained at the top of the refining tower.

The invention relates to a refining method of dicyclohexylamine, belonging to the technical field of organic chemistry.

Cyclohexanol gas-phase ammoniation method: it is the liquid hydrogenation of cyclohexanol and ammonia to cyclohexanamine and dicyclohexanamine under the action of nickel/silica catalyst. The yield of cyclohexanol and dicyclohexanamine is 3:1, and the conversion rate of cyclohexanol is about 70%, which has not been reported in industrialization in China.

At present, there are few reports on the quantitative analysis of dicyclohexylamine and impurities, so it is necessary to study them separately accurate quantitative analysis method. Since dicyclohexylamine has no ultraviolet absorption, the quantitative analysis method of dicyclohexylamine by high performance liquid chromatography evaporative light scattering detector was studied. 

It is obtained by catalytic hydrogenation of aniline and can be divided into atmospheric pressure method and pressure method. In addition, cyclohexamine can be prepared by catalytic ammonolysis of cyclohexane or cyclohexanol, reduction of nitrocyclohexane, and catalytic ammonolysis of cyclohexanone in the presence of hydrogen.The refining process often contains impurities such as aniline and water.

The invention relates to a method for the synthesis of N-chlorinated dicyclohexylamine with low concentration of sodium hypochlorite. The mass of dicyclohexylamine is weighed, and the amount of sodium hypochlorite of low concentration required for the reaction is calculated according to the molar ratio of dicyclohexylamine and sodium hypochlorite =1:1.051.20. Put dicyclohexylamine into the reactor, and keep the reactor temperature.

Dicyclohexylamine has the chemical properties of a secondary amine. It has a strong base and can form salts with various acids. Acylation may occur. In terms of solubility, dicyclohexylamine is slightly soluble in cold water but almost insoluble in hot water. Dry powder, carbon dioxide, soluble foam and sand are used to extinguish the fire.

The purity of dicyclohexylamine is higher than ninety nine.5%, that is 99% better than the same old of peer groups. recycling the economic chain can lessen the comprehensive price of the producing facility. there are three aniline factories in dongying, shandong, huai 'an, jiangsu and tianji, shanxi within four hundred kilometers. the era is mature, and the people have about 20 years of practical enjoy.

The purity of dicyclohexylamine is better than 99.five%, that is 99% higher than the standard of peer organizations. recycling the economic chain can lessen the comprehensive value of the manufacturing facility. there are 3 aniline factories in dongying, shandong, huai 'an, jiangsu and tianji, shanxi within four hundred kilometers. the generation is mature, and the people have about twenty years of practical enjoy.

The method of species co-production of cyclohexylamine and dicyclohexylamine and the catalyst system used for the method. The method includes the following steps :(1) the raw material aniline, cyclohexanone, ammonia, hydrogen after the loading load RhNi catalyst first section reactor, the first reaction liquid.(2) The reaction solution containing cyclohexylamine and dicyclohexylamine was obtained through the second stage reactor loaded with RhCo catalyst.

The purity of dicyclohexylamine is higher than 99.5%, which is 99% higher than the standard of peer enterprises. Recycling the industrial chain can reduce the comprehensive cost of the factory. There are three aniline factories in Dongying, Shandong, Huai 'an, Jiangsu and Tianji, Shanxi within 400 kilometers. The technology is mature, and the workers have about twenty years of practical experience. Stable supply, with an annual output of 36,000 tons, of which dicyclohexylamine has an annual output of 12,000 tons.

The purity of dicyclohexylamine is better than ninety nine.5%, this is 99% higher than the identical old of peer companies. recycling the economic chain can reduce the complete fee of the manufacturing facility. there are 3 aniline factories in dongying, shandong, huai 'an, jiangsu and tianji, shanxi within 4 hundred kilometers. the technology is mature, and the human beings have approximately twenty years of realistic experience.

Nitrocyclohexane reduction method: This method takes nitrocyclohexane and hydrogen as raw materials, using reducing agent to generate cyclohexylamine, because nitrocyclohexane raw materials are difficult to obtain, this method is basically eliminated. Moreover, the process has some defects, such as low one-way conversion of aniline and poor selectivity of dicyclohexylamine.

The invention uses nitro-benzene and hydrogen as raw materials. Adding solvent, nitro-benzene and catalyst into the reaction kettle, controlling the reaction pressure of 0.5 ~ 4MPa, reaction temperature of 60 ~ 160℃, reaction for 2 ~ 8h, cyclohexylamine and dicyclohexylamine are obtained, and the catalyst used is Pd/CNTs catalyst or PD-Ni /CNTs catalyst. 

A vapor phase corrosion inhibitor preparation method, including the following steps :a. Dispersing montmorillonite in deionized water, beating, stirring, and then taking the suspension of the solution to add morpholine, heating the solution to evaporate and precipitate crystals.b. Add formaldehyde to the solution in Step a and let it stand; add dicyclohexylamine and let it stand; then add the mixed solution of benzoic acid and acetone to the solution and let it stand to generate white slurry.

The production process of trichlorosilane is mostly prepared by reaction of gold-grade silicon metal powder and hydrogen chloride gas in a fluidized bed reactor. Generally using gold grade metal silicon powder, hydrogen chloride gas by the combustion reaction of chlorine and hydrogen gas. Reaction temperature is 300-400 degrees, most of the pressure using micro positive pressure operation.

In silicon tetrachloride purification, boron is the most difficult impurity to remove. Researchers have proposed compound method to remove boron from silicon tetrachloride, which has achieved satisfactory results and has been widely used in industrial production.

At present, there are two main synthesis methods of trichlorosilane: one is the traditional synthesis method, that is the silicon chloride method. The other is hydrolyzation of tetrachloride. At present, the mainstream method of polysilicon production is the modified Siemens method, using trichlorosilane reduction method. In recent years, with the continuous decline of polysilicon price, polysilicon production enterprises pay more and more attention to the control of production cost.

The mixture of trichlorosilane and polysilicon, which is a by-product of the recombination from the bottom of the distillation column in the production of trichlorosilane and polysilicon, was used as raw material to prepare silica by gas phase hydrolysis. The effects of gasification temperature, flow rate and flow ratio of water vapor and chlorosilane mixture on physicochemical properties of the products were investigated.

A sulfonate of cyclohexylamine; used as an artificial flavoring in food, beverages, and medicine. Also used as an acid gas absorber. Used as a pH regulator for boiler feed water. Cyclohexylamine is a volatile substance that can easily reach the whole system after dosing.If pH is lower than 8.5, the treatment effect of cyclohexylamine is not good. Synthetic desulfurizer, rubber promoter, dye, antistatic agent, corrosion inhibitor, pesticide fungicide, insecticide and other intermediates. Used as boiler water treatment agent, corrosion inhibitor, rubber promoter, etc.

A method of cyclohexylamine catalytic production of biodiesel with prickly ash seed oil as raw material is described as follows: prickly ash seed oil is mixed with methanol and the catalyst cyclohexylamine.