Cyclohexylamine, an organic compound with the chemical components of c6h13n, is a drab to yellow liquid, soluble in water and miscible in most organic solvents. It is mainly used as a solvent, and can also be used to prepare desulfurizer, rubber antioxidant, vulcanization accelerator (CZ), cyclamate, medical raw materials, chemical additives for plastics and textiles, boiler feed water treatment agent, metal corrosion inhibitor, emulsifier, preservative, antistatic agent and latex coagulant.
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A sulfonate of cyclohexylamine; used as an artificial flavoring in food, beverages, and medicine. Also used as an acid gas absorber. Used as a pH regulator for boiler feed water. Cyclohexylamine is a volatile substance that can easily reach the whole system after dosing.If pH is lower than 8.5, the treatment effect of cyclohexylamine is not good. Synthetic desulfurizer, rubber promoter, dye, antistatic agent, corrosion inhibitor, pesticide fungicide, insecticide and other intermediates. Used as boiler water treatment agent, corrosion inhibitor, rubber promoter, etc.
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The method of species co-production of cyclohexylamine and dicyclohexylamine and the catalyst system used for the method. The method includes the following steps :(1) the raw material aniline, cyclohexanone, ammonia, hydrogen after the loading load RhNi catalyst first section reactor, the first reaction liquid.(2) The reaction solution containing cyclohexylamine and dicyclohexylamine was obtained through the second stage reactor loaded with RhCo catalyst.
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Cyclohexylamine, an organic compound with the chemical formula of C6H13N, is a colorless to yellow liquid, soluble in water and miscible in most organic solvents. UsageIt is mainly used as solvent, and can also be used to prepare desulfurizer, rubber antioxidant, vulcanization accelerator, chemical additives for plastics and textiles, boiler feed water treatment agent, metal corrosion inhibitor, emulsifier, preservative, antistatic agent, latex coagulant, petroleum additive, bactericide, insecticide and dye intermediate.SpecificationProjectItemBest gradeFirst grade
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The invention uses nitro-benzene and hydrogen as raw materials. Adding solvent, nitro-benzene and catalyst into the reaction kettle, controlling the reaction pressure of 0.5 ~ 4MPa, reaction temperature of 60 ~ 160℃, reaction for 2 ~ 8h, cyclohexylamine and dicyclohexylamine are obtained, and the catalyst used is Pd/CNTs catalyst or PD-Ni /CNTs catalyst.
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Devices that use tail gas to recover cyclohexylamine are characterized in that they include: spray tower, circulating pump, condenser, defogger, photooxygen catalytic oxidizer, ozone treatment device, blower, chimney. Described in the circulating pump and spray the bottom connection, as described in the other side of the circulating pump are connected to the condenser, the condenser and the upper spray tower connection, described in the spray tower are connected to the top of demister, described in the mist bottom and photocatalytic oxidation, photocatalytic oxidation is described, ozone
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A method of cyclohexylamine catalytic production of biodiesel with prickly ash seed oil as raw material is described as follows: prickly ash seed oil is mixed with methanol and the catalyst cyclohexylamine.
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The purity of hydrogen is high, and the purity of cyclohexylamine reaches over 99.95%, which is higher than the industry standard by 99.8%. The purity of dicyclohexylamine is higher than 99.5%, which is 99% higher than the standard of peer enterprises. Recycling the industrial chain can reduce the comprehensive cost of the factory. There are three aniline factories in Dongying, Shandong, Huai 'an, Jiangsu and Tianji, Shanxi within 400 kilometers. The technology is mature, and the workers have about twenty years of practical experience.
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Cyclohexylamine has the chemical properties of a primary amine. Carbonates that are strongly alkaline and absorb carbon dioxide in the air to form white crystals. It can react with acyl chloride, anhydride and ester to form N-acyl. React with nitrite to give alcohol. Hydroxymethyl compounds are formed by reaction with formaldehyde in alkaline solution. Reacts with carbon disulfide to form dithiocarbamate. Reacts with aldehydes to form Schiff bases.This product is used to prepare cyclohexanol, caprolactam, acetate fiber and nylon 6, etc.
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By controlling the parameters in each step, such as time, temperature, pressure, etc.The yield of cyclohexylamine products is high, the product yield is more than 99%, the quality is stable, the yield is high, the production capacity is large, the side reaction is less, and a small amount of by-product dicyclohexylamine in the reaction can be recovered and purified, and the added value of the products can be increased.
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The process relates to a tail gas refining method, in particular to the hydrogenation of aniline to prepare cyclohexylamine and the deamination of dicyclohexylamine tail gas to refine hydrogen.
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It is obtained by catalytic reduction of nickel or cobalt from aniline at high temperature and pressure. Cyclohexanol can also be reduced by phenol, oxidized to cyclohexanone, and then aminated with ammonia to obtain cyclohexanamine.This substance is harmful to the environment, and special attention should be paid to the pollution of water bodies. Acute poisoning may occur by inhalation of vapour. Irritant and corrosive to skin, eyes and mucous membranes, and can cause allergy through skin absorption.
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Trichlorosilane is mainly used in the manufacture of polysilicon and silane coupling agents, among which polysilicon is the most important downstream application area of trichlorosilane, accounting for 32% of the consumption in 2021, and silane coupling agent consumption accounted for 25%. The market is still in good condition.
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With the rapid growth of downstream PV demand, photovoltaic grade trichlorosilane continues to be in short supply. The application of PV grade trichlorosilane in the production of polysilicon includes a one-time requirement for the first commissioning, which accounts for about 20% of the total capacity. Second, the requirement for chlorine supplementation during continuous production accounts for about 10 to 30 percent of total production. On the supply side, the expansion of trichlorosilane production has been conservative in the past.
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To explore the application value of ion chromatography in the detection of cyclohexylamine in workplace air. Workplaces containing cyclohexylamine in the production of raw materials were selected as sampling sites, and the content of cyclohexylamine in workplaces was detected by ion chromatography. At the same time, the precision and recovery rate of ion chromatography, desorption efficiency, sampling efficiency and other cation interference characteristics were analyzed.
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It is obtained by catalytic hydrogenation of aniline and can be divided into atmospheric pressure method and pressure method. In addition, cyclohexamine can be prepared by catalytic ammonolysis of cyclohexane or cyclohexanol, reduction of nitrocyclohexane, and catalytic ammonolysis of cyclohexanone in the presence of hydrogen.The refining process often contains impurities such as aniline and water.
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Cyclohexylamine (CHA) is a primary amine, can be miscible with water with infinite ratio, the molecule is small, easy to adsorb on the metal surface, its shielding effect is better than long chain primary amine and secondary amine, so it can effectively prevent the invasion of corrosive ions, thereby improving corrosion resistance, especially the ability to inhibit corrosion.The corrosion inhibition of 304 stainless steel by cyclohexylamine in sodium chloride medium was studied in detail.
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The main by-product of trichlorosilane, silicon tetrachloride, is also the main raw material for the manufacture of silicone, its finished products are silicone ester, silicone oil, high temperature insulating paint, silicone resin, silicone rubber and heat resistant cushion lining materials. High purity silicon tetrachloride is also an important raw material for manufacturing high purity silicon dioxide, inorganic silicon compounds, quartz fibers and optical fibers.
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The invention relates to a method for the synthesis of N-chlorinated dicyclohexylamine with low concentration of sodium hypochlorite. The mass of dicyclohexylamine is weighed, and the amount of sodium hypochlorite of low concentration required for the reaction is calculated according to the molar ratio of dicyclohexylamine and sodium hypochlorite =1:1.051.20. Put dicyclohexylamine into the reactor, and keep the reactor temperature.
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The invention relates to a tail gas refining method, especially a method for hydrogenation of aniline to produce dicyclohexylamine tail gas deamination and hydrogen refining, which belongs to the technical field of chemical industry.
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Foreign production and application are mainly concentrated in the western developed countries and regions, the main manufacturers are the United States Air Products company, Celanes company, Germany BASF, Bayer company and other scale manufacturers. But in Europe, cyclohexylamine has been in short supply due to the limitation of hydrogen feedstock. With the rapid development of the food additive cyclamate and rubber industry, the consumption of cyclohexylamine has been increasing at an average annual rate of more than 10%.
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SiCl4 is one of the most important inorganic silicon compounds, is a colorless, transparent, flowing smoke liquid, with suffocating odor, soluble in benzene, ether, chloroform and other most organic solvents. Silicon tetrachloride is a volatile liquid with strong asphyxiating odor. It can be used as raw materials for the production of gaseous silica, high purity silicon and organosilicide. The upstream of the silicon tetrachloride industry chain is the raw material market, mainly silicon powder, ferrosilicon, hydrogen chloride, etc.
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Silane coupling agent product price growth is very obvious, compared with the same period last year growth of 118%. Upstream raw material trichlorosilane price rise, silane products for the high price operation provides a strong support. Reporters learned that trichlorosilane is mainly used in the production of polysilicon, silane coupling agent, silane coupling agent is the second largest downstream market of trichlorosilane, in recent years the demand is more exuberant.
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Silicon tetrachloride is mainly used in the manufacture of silicone esters, gaseous silica, silicone monomer, silicone oil, high temperature insulating paint, silicone resin, silicone rubber and so on. High-purity silicon tetrachloride is the main raw material for manufacturing fiber prefabricated rod, and the quality of fiber prefabricated rod directly determines the fiber performance. Therefore, high-purity silicon tetrachloride is the core raw material of fiber industry.
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